آخرین محصولات

Investigation of the mechanism and effect of temperature on the

In this article, the catalytic conversion of oxygenated compounds (methyl acetate and 4-heptanone) to gasoline has been studied over NH4-ZSM-5 catalyst (Si/Al = 80) at three temperatures of 250, 300, and 390 °C. To determine the crystalline structure and acid sites of the catalyst, X-ray diffraction analysis (XRD) and NH3-TPD analysis …

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Chemistry Proceedings | Free Full-Text | ZnO-Incorporated ZSM-5 …

The morphology of ZSM-5 has a hexahedral structure, in agreement with the ZSM-5 characteristics from a previously reported study . By incorporating ZnO into ZSM-5, the surface was covered with a small amount of nano-scale ZnO particles, which led to the differentiation of ZSM-5 particles.

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ZSM-5 | Zeolyst International Zeolyst International

ZSM-5, CBV2314, CBV3024E, CBV5524G, CBV8014, CBV28014. Zeolyst Products SiO 2 /Al 2 O 3 Mole Ratio Nominal Cation Form Na 2 O Weight % Surface Area, m 2 /g Download SDS; CBV 2314

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NH4-exchanged zeolites: Unexpected catalysts for

NH 4-, H-, Na-, Cs-exchanged ZSM-5 zeolites have been investigated as catalysts for the selective oxidation of cyclohexane under mild conditions using molecular oxygen as oxidant.For comparison, Mn- and Fe-exchanged ZSM-5 zeolites were also studied, as Mn and Fe are well-known oxidation metals. It has been shown that the type …

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Ceramic Processing Techniques for Catalyst Design: Formation

Volume 9, Issue 5 p. 902-910. Original Article. Ceramic Processing Techniques for Catalyst Design: Formation, Properties, and Catalytic Example of ZSM-5 on 3-Dimensional Fiber Deposition Support Structures. Jasper Van Noyen, Corresponding Author. Jasper Van Noyen. Department of Materials Technology, Flemish Institute for …

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Zeolite-based catalysts for methanol to gasoline process: A review

MTG process was conducted for the first time by Mobil Co. in 1970 using synthetic zeolites called ZSM-5. At optimized process conditions (e.g. temperature about 400 ºC and pressure 15–25 atm), the commercial plant can produce hydrocarbons in gasoline range with 80% selectivity, and the rest of product being mainly LPG [8, 9]. ZSM …

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Improving the Hydrothermal Stability of ZSM-5 Zeolites in 1 …

For the aromatization of olefins (in Fischer–Tropsch synthetic oil), especially for the fluidized bed reaction with steam as the fluidized medium, improving the catalytic and hydrothermal stabilities of ZSM-5 catalysts is a research focus because of both fundamental research interests and potential commercial applications. In this work, sequential alkali …

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The Nanostructure Zeolites MFI-Type ZSM5 | IntechOpen

The development of new porous solids begins to provide effective and original solutions to the problems of pollution and sustainable development, and the challenge is to discover new performance of these materials. Among these materials are zeolites; however, one type has retained the attention since its discovery in 1972; this is zeolite-type ZSM-5, …

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Rapid hydrothermal synthesis of hierarchical ZSM-5/beta …

An innovative hydrothermal method has been successfully applied to the synthesis of hierarchical ZSM-5/beta composite zeolites with different mass ratios. Firstly, the ZSM-5 …

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Applied Sciences | Free Full-Text | Adsorption of CO2 on ZSM-5 …

In this paper, a synthesized zeolite (ZSM-5) is used as an adsorbent to analyze the adsorption phenomenon of carbon dioxide. This investigation, based on the statistical physics treatment, applied the multilayer model with saturation to understand the CO2 adsorption on four samples, namely M-ZSM-5 (M = Na+, Mg2+, Zn2+, La3+), at …

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Ga/ZSM-5 Catalyst Improves Hydrocarbon Yields and …

ZSM-5 are encouraging, there is a need to further improve upon this baseline catalyst to generate alkenes at higher yields. Doping of ZSM-5 catalysts with various metals has been evaluated for CFP to increase hydrocarbon yields. For example, ZSM-5 modified with nickel and cobalt were evaluated for upgrading beech pyrolysis vapors. The

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ZSM-5

The ZSM-5 molecular sieve is a highly siliceous aluminosilicate zeolite with an intersecting and three-dimensional channel system. Its chemical formula, Na n Al n Si 96-n O 192 · 16H 2 O, shows …

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Faculty Profile

Mechanochemical Reaction Pathways in Solvent-Free Synthesis of ZSM-5, Majid Nada, Edward Gillan and Sarah C. Larsen, Microporous and Mesoporous Materials, ... Sarah C. Larsen, in Encyclopedia of Analytical Chemistry, eds R.A. Meyers, John Wiley: Chichester. UK, DOI: 9780470027318. 2011, p/ 1522-1548;

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Applied Sciences | Free Full-Text | Experimental Study on the

Herein, a series of Co-Fe mixed oxide modified ZSM-5 adsorbents were synthesized using the ultrasonic-assisted impregnation method for the capture of elemental mercury. In comparison with other samples, Co4Fe1-ZSM-5 produced a relatively better performance, with the removal efficiency of around 96.6% Hg0 and the adsorption …

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Role of Al in Na-ZSM-5 zeolite structure on catalyst stability in

1 Altmetric Metrics Abstract The Na-ZSM-5 catalysts (SiO 2 /Al 2 O 3 molar ratio = 20, 35, and 50) were prepared by rapid crystallization method to investigate their …

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Frontiers | Synthesis of Ni-Modified ZSM-5 Zeolites and Their …

Ni-modified ZSM-5 zeolites with different nickel contents were successfully prepared by the in situ synthesis method and the impregnation method. The synthesized samples were characterized by XRD, SEM, N2 adsorption–desorption isothermals, and Py-FTIR. The characterization results show that both the textural properties and …

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The ZSM-5-Catalyzed Oxidation of Benzene to Phenol with N

The oxidation of benzene to phenol (BTOP) with N2O as the oxidant has been studied with a variety of Fe/ZSM-5 catalysts. The literature has conclusively proven that Fe2+ sites are the active sites. However, some studies have suggested that the Lewis acidic sites (LAS) are responsible for the generation of the active chemisorbed oxygen. …

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Resolving the Acid Site Distribution in Zn-Exchanged ZSM-5 with …

Zeolites are widely used acid catalysts in research and in industrial processes. The catalytic performance of these materials is affected by the nature and concentration of Brønsted and Lewis acid sites. The balance between these types of active sites—and thus the activity and selectivity of the zeolite—can be altered by the …

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PVA-Based Mixed Matrix Membranes Comprising ZSM-5 for …

The traditional ion-exchange membranes face the trade-off effect between the ion flux and perm-selectivity, which limits their application for selective ion separation. Herein, we amalgamated various amounts of the ZSM-5 with the polyvinyl alcohol as ions transport pathways to improve the permeability of monovalent cations and exclusively …

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Hierarchical ZSM-5 catalytic performance evaluated in the …

Hierarchical ZSM-5 catalysts with different Si/Al ratios (20, 60 and 100) were hydrothermally synthesized. The prepared samples were studied by several techniques, including X-ray diffraction (XRD), X-ray fluorescence (XRF) analysis, Fourier transform infrared (FTIR) spectroscopy, N 2 adsorption–desorption, high resolution transmission …

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what is zsm-5 zeolite – zsm-5 zeolite catalyst

The structure of ZSM-5 zeolite by showing the coordination tetrahedron. Electron micrograph of MFI zeolite with the structural model overlaid in the right-bottom corner.[1] ZSM-5 From Wikipedia, the free encyclopedia. The molecular structure of ZSM-5 zeolite, showing well defined pores and channels in the zeolite. Yellow balls represent Si …

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ZSM-5

ZSM-5, Zeolite Socony Mobil–5 ), is an aluminosilicate zeolite belonging to the pentasil family of zeolites. Its chemical formula is NanAlnSi96–nO192·16H2O . Patented by Mobil Oil Company in 1975, it is widely used in the petroleum industry as a heterogeneous catalyst for hydrocarbon isomerization reactions.

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Direct synthesis of HZSM-5 zeolites with enhanced

The mixture was then transferred into an autoclave and crystallized at 180 °C for 48 h. The H-form ZSM-5 zeolites were directly obtained after filtration, drying, and heating at 550 °C for 4 h. These new H-form ZSM-5 zeolites were labeled as Z5-N1, Z5-N2, and Z5-N3, corresponding to x = 50, 100, and 200, respectively. 2.3. Characterization

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History of ZSM-5 fluid catalytic cracking additive development at …

ZSM-5 has found widespread application as a fluid catalytic cracking additive for both propylene production and gasoline octane improvement. This paper traces its …

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272-5652ndd

ZSM-5 crystallises in the idealised orthorhombic system with space group Pnma and lattice constants a = 20.1, b = 19.9, and c = 13.4A; monoclinic symmetry has also been

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The Nanostructure Zeolites MFI-Type ZSM5 | IntechOpen

The MFI (Mobil-type five) zeolites chosen as model adsorbents in this chapter are zeolites ZSM-5 (Zeolite Socony Mobil-type 5) ; they were synthesized for the first …

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ZSM-5 Additive

Patent application title: ZSM-5 Additive Inventors: Gary M. Smith (Verona, NJ, US) Barry K. Speronello (Montgomery, NJ, US) IPC8 Class: AC07C402FI USPC Class: 585651 Class name: By c content reduction, e.g., cracking, etc. ethylene product per se using catalyst Publication date: Patent application number: 20090023971

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ZSM-5

ZSM-5 - Zeolite Socony Mobil 5, (structure type MFI mordenite framework inverted) is an aluminosilicate zeolite mineral belonging to the pentasil family of zeolites. Its chemical …

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Frontiers | Synthesis of Ni-Modified ZSM-5 Zeolites …

Ni-modified ZSM-5 zeolites with different nickel contents were prepared by two different methods, namely, in situ synthesis and impregnation methods. The XRD and SEM analyses showed that ZSM-5 …

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Rapid hydrothermal synthesis of hierarchical ZSM-5/beta …

Introduction ZSM-5 zeolite is a porous silicoaluminate with a unique two-dimensional structure of 10-membered ring channels. 1 ZSM-5 has been widely used in the fields of catalysis, adsorption and separation in industry because of its excellent features such as strong acidity, superior hydrothermal stability, unique shape selectivity and so on. 2,3 …

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